12354-85-7

Reaction

Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids. Catalyst used in the asymmetric transfer hydrogenation of imines in water. Facile rhodium-catalyzed synthesis of fluorinated pyridines. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Who Evaluation

Evaluation year: 2016

EXPOSURE ROUTES

inhalation, skin absorption, ingestion, skin and/or eye contact

FIRST AID

(See procedures) Eye:Irrigate immediately Skin:Soap flush immediately Breathing:Respiratory support Swallow:Medical attention immediately

Consumer Uses

ECHA has no public registered data indicating whether or in which chemical products the substance might be used. ECHA has no public registered data on the routes by which this substance is most likely to be released to the environment.