563-04-2

  • Product Name:TRI-M-TOLYL PHOSPHATE
  • Molecular Formula:C21H21O4P
  • Purity:99%
  • Molecular Weight:368.369
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Product Details

  • CasNo: 563-04-2
  • Molecular Formula: C21H21O4P
  • Appearance: Clear very slightly yellow to pink liquid
  • Factory Sells Factory Supply TRI-M-TOLYL PHOSPHATE 563-04-2 Safe Transportation

    • Molecular Formula:C21H21O4P
    • Molecular Weight:368.369
    • Appearance/Colour:Clear very slightly yellow to pink liquid 
    • Vapor Pressure:1.38E-07mmHg at 25°C 
    • Melting Point:25.5°C 
    • Refractive Index:1.555-1.557  
    • Boiling Point:441.7 °C at 760 mmHg 
    • Flash Point:234.3 °C 
    • PSA:54.57000 
    • Density:1.201 g/cm3 
    • LogP:6.25670 

    TRI-M-TOLYL PHOSPHATE(Cas 563-04-2) Usage

    Chemical Properties

    CLEAR VERY SLIGHTLY YELLOW TO PINK LIQUID

    General Description

    Wax. When mixed with its isomers (ortho and meta ), the result is a colorless, odorless liquid.

    Air & Water Reactions

    May hydrolyze under alkaline conditions. . Insoluble in water.

    Reactivity Profile

    Organophosphates, such as TRI-M-TOLYL PHOSPHATE, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

    Fire Hazard

    Combustible

    InChI:InChI=1/C21H21O4P/c1-16-7-4-10-19(13-16)23-26(22,24-20-11-5-8-17(2)14-20)25-21-12-6-9-18(3)15-21/h4-15H,1-3H3

    563-04-2 Relevant articles

    Diphenyl Diselenide-Catalyzed Synthesis of Triaryl Phosphites and Triaryl Phosphates from White Phosphorus

    Zhang, Yue,Cai, Ziman,Chi, Yangyang,Zeng, Xiangzhe,Chen, Shuanghui,Liu, Yan,Tang, Guo,Zhao, Yufen

    , p. 5158 - 5163 (2021/07/20)

    Industrially important triaryl phosphite...

    Nickel-catalyzed amination of aryl phosphates through cleaving aryl C-O bonds

    Huang, Jin-Hua,Yang, Lian-Ming

    supporting information; experimental part, p. 3750 - 3753 (2011/09/14)

    The amination of triaryl phosphates was ...

    Microwave-assisted synthesis of triaryl phosphates

    Sagar,Shinde,Bandgar

    , p. 269 - 271 (2007/10/03)

    -

    Absolute viscosity and density of trisubstituted phosphoric esters

    Kannan,Kishore

    , p. 649 - 655 (2007/10/03)

    This paper presents measurements on the ...

    563-04-2 Process route

    3-methyl-phenol
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    3-methyl-phenol

    tri-m-cresyl phosphate
    563-04-2

    tri-m-cresyl phosphate

    Conditions
    Conditions Yield
    With sodium hydroxide; trichlorophosphate; for 2.5h; Microwave irradiation;
    87%
    With trichlorophosphate;
    With sodium hydroxide; dibenzo-18-crown-6; trichlorophosphate; N-benzyl-N,N,N-triethylammonium chloride; Yield given. Multistep reaction; 1.) H2O, CHCl3, 2.) H2O, CHCl3, 20 min;
    With triethylamine; trichlorophosphate; In toluene; at 0 - 20 ℃; Inert atmosphere;
    Multi-step reaction with 2 steps
    1: phosphorus; potassium phosphate; diphenyl diselenide / toluene; dimethyl sulfoxide / 6 h / 60 °C / Schlenk technique; Inert atmosphere
    2: dihydrogen peroxide / toluene; dimethyl sulfoxide / 0.5 h / 20 °C / Schlenk technique
    With potassium phosphate; diphenyl diselenide; phosphorus; dihydrogen peroxide; In dimethyl sulfoxide; toluene;
    sodium 3-methylphenoxide
    3019-89-4

    sodium 3-methylphenoxide

    tri-m-cresyl phosphate
    563-04-2

    tri-m-cresyl phosphate

    Conditions
    Conditions Yield
    With Amberlyst A-26 chloride; trichlorophosphate; In benzene; for 1.08333h; Ambient temperature;
    92%
    With tetrabutylammomium bromide; In chloroform; water;

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    Purity:99%

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